Synthesis of 1,2-bis(methoxyamino)cycloalkanes from alicyclic 1,2-bis(hydroxyamines) |
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| Authors: | D. G. Mazhakin V. K. Khlestkin A. Ya. Tikhonov L. B. Volodarsky |
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| Affiliation: | (1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. akad. Lavrent'eva, 630090 Novosibirsk, Russian;(2) Novosibirsk State University, 2 ul. Pirogova, 630090 Novosibirsk, Russian |
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| Abstract: | Derivatives of 1,4-dihydroxypiperazine-2,3-dione were obtained by reaction of cis-1,2-bis(hydroxyamino)cycloalkanes with diethyl oxalate. Their alkylation with CH2N2 or Mel afforded 1,4-dimethoxypiperazine-2,3-diones. Hydrolysis of the latter gave 1,2-bis(methoxyamino)cycloalkanes.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 925–929, April, 1996. |
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| Keywords: | 1,2-bis(hydroxyamines) 1,2-bis(methoxyamines) 1,2-bis(methoxyamino)cycloalkanes piperazinediones cyclic hydroxamie acids alkylation hydrolysis |
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