The thermal decompositions of some transition metal acrylates and polyacrylates |
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Authors: | A Gronowski Z Wojtczak |
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Institution: | (1) Institute of Chemistry, N. Copernicus University, 87-100 Toru , Poland |
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Abstract: | The thermal behaviours of zinc, cobalt, nickel and copper acrylates and their polymers were investigated. It was found that the decompositions of these compounds are complex processes. The main decomposition of the monomer was preceded by thermal polymerization. The thermal effect of this reaction was greater for zinc acrylate than for the other salts. The reaction orders and activation energies of decomposition of the monomers and the polymers were calculated and the differences discussed.
Zusammenfassung Das thermische Verhalten der Acrylate von Zink, Kobalt, Nickel und Kupfer und das der entsprechenden Polymere wurde untersucht. Es wurde festgestellt, dass die Zersetzung dieser Verbindungen komplexe Prozesse sind.Der Zersetzung der Monomeren ging eine thermische Polymerisation voraus. Der thermische Effekt dieser Reaktion war im Falle des Zinkacrylats grösser als bei den anderen Salzen. Die Reaktionsordnungen und Aktivierungsenergien der Zersetzung der Monomeren und Polymeren wurden berechnet und die Unterschiede diskutiert.
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