Zum Aufbau Schlecht geordneter Calciumhydrogensilicate. II. Über eine aus Poly- und Disilicat bestehende Phase

On the Structure of Ill-crystallized Calcium Hydrogen Silicates. II. A Phase Consisting of Poly and Disilicate Both by condensation reactions of a calcium hydrogen disilicate phase [1] under the mother liquid at 80°C and by hydrothermal reactions of lime and silica at 150°C an ill-crystallized calcium hydrogen silicate phase is formed, being built up by nearly equal parts (referred to Si) of poly-and disilicate anions. The CaO content of the phase synthesized at 80°C varies between 1.1 and 2CaO/SiO₂, depending on the Ca(OH)₂ concentration in the mother liquid. In the phase formed at 150°C is CaO/SiO₂ = l.l–l.5. A proposal for the constitution of this phase is given.