CuAl2Cl8. Darstellung und Kristallstruktur |
| |
Authors: | Harald Sch afer,Michael Binnewies,Reinhard Laumanns,Heinrich W chter |
| |
Affiliation: | Harald Schäafer,Michael Binnewies,Reinhard Laumanns,Heinrich Wächter |
| |
Abstract: | CuAl2Cl8. Preparation and Crystal Structure. Crystals of CuAl2Cl8 have been prepared. Their remission spectrum agrees with that of gaseous CuAl2Cl8. The crystal structure (P21/c;a = 6.614, b = 7.376, c = 12.319 Å; β = 94.11°) shows a molecular lattice with Cu in square planar coordination, which is completed to a stretched octahedron (as in solid CuCl2) by two Cl atoms from neighbour molecules. Al has tetrahedral coordination. |
| |
Keywords: | |
|
|