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Beiträge zur Chemie des Phosphors. 94. Tetraphenyl-cyclotetraphosphan, (PPh)4, und 1,2,3-Triphenyl-4-tert-butyl-cyclotetraphosphan, (PPh)3(PBut)
Authors:M Baudler  G Reuschenbach
Abstract:Contributions to the Chemistry of Phosphorus. 94. Tetraphenyl-cyclotetraphosphane, (PPh)4, and 1,2,3-Triphenyl-4-tert-butyl-cyclotetraphosphane, (PPh)3(PBut) The homocyclic four-membered phosphorus ring compounds tetraphenyl-cyclotetra-phosphane, (PPh)4 ( 1 ), and l,2,3-triphenyl-4-tert-butyl-cyclotetraphosphane, (PPh)3(PBut) ( 2 ), are obtained as main products by 3+l]-cyclocondensation of K(Ph)P? P(Ph)? P(Ph)K or Me3Si(Ph)P? P(Ph)? P(Ph)SiMe3 with PhPCl2 or ButPCl2 respectively under suitable reaction conditions. At room temperature in solution 1 rearranges mostly to the oligomeric (PPh)5, whereas 2 is remarkably stable. The 31P-NMR parameters of the mixed substituted four-membered ring compound 2 are reported and discussed.
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