Strukturuntersuchungen an SIVN3-Gruppierungen. IV [1-3] |
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Authors: | A. Gieren B. Dederer I. Abelein |
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Affiliation: | Fachbereich Chemie d. Univ., Lahnberge, D-3550 Marburg |
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Abstract: | N-chloralkyl-nitridochloro Complexes of Molybdenum (VI). [Cl5MoN-R]− with R = CCl3, C2Cl5. Crystal Structure of (AsPh4)2[(MoOCl4)2CH3CN] In the reaction of tetraphenyl arsonium chloride with the complexes Cl3PO (Cl4)-MoN R (R=CCl3, C2Cl5) the POCl3 is displaced by chloride and yields [Cl5MoN R] −. From the i.r. spectra a structure with six-coordinated molybdenum and a MoN triple bond can be deduced. By reaction with water in acetonitrile the molybdenum is reduced to Mo(V) and the nitride ligand is removed yielding (AsPh4)2[(MoOCl4)2CH3CN]. The crystal structure of this compund was determined with X-ray diffraction data. In the tetragonal structure (space group P4/n) AsPh4+ cations and two different anions were found: square pyramidal [MoOCl4]− and [MoOCl4 · NCCH3]− in which the nitrile is bonded in trans position to the oxygen. The short Mo O distances of 165 pm indicate a strong π-bonding. |
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