Einlagerungsreaktionen von Biscyclopentadienyl-Vanadium und -Mangan mit Eisenoxidchlorid in etherischer Lösung

Intercalation Compounds of Manganocene and Vanadocene with FeOCl in Ether Solution The recently synthesized FeOCl intercalation compounds from Cp₂Mn and Cp₂V proved that in the case of the vanadium compounds the Fe³⁺ centers of the FeOCL host-lattice were partly reduced to Fe₂₊. In comparison to the bulk FeOCl, the central doublet in the Mößbauer spectra of the FeOCl intercalation compounds with NH₃, pyridine, 4-amino-pyridine, manganese and vanadium compounds indicates – with respect to the biscyclopentadienyl transition metal FeOCl intercalation compounds (M = Cr, Fe, Ni, Co) – a small chemical shift to higher energies and a degradation of the quadrupol splitting.