Untersuchung der Cokristallisation in den Systemen. Mn(OOCCH3)2-Co(OOCCH3)2-H2O,Mn(OOCCH3)2-Ni(OOCCH3)2-H2O,Mn(OOCCH3)2-Zn(OOCCH3)2-H2O bei 60°C |
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| Authors: | D Stoilova |
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| Abstract: | Investigation of Cocrystallization in the Systems Mn(OOCCH3)2-Co(OOCCH3)2-H2O, Mn(OOCCH3)2-Ni(OOCCH3)2-H2O, Mn(OOCCH3)2-Zn(OOCCH3)2-H2O at 60°C The three-component systems Mn(OOCCH3)2-Co(OOCCH3)2-H2O, Mn(OOCCH3)2-Ni(OOCCH3)2-H2O and Mn(OOCCH3)2-Zn(OOCCH3)2-H2O at 60°C were investigated by physio-chemical analysis. There is an interruption in the series of mixed crystals formed in the three-component systems. The inclusion of Co2+- and Ni2+ in Mn(OOCCH3)2 · 2 H2O of Mn2+ in Co(OOCCH3)2 · 2 H2O, Zn(OOCCH3)2 · 2 H2O and Ni(OOCCH3)2 · 4 H2O is based on isodimorphic substitution. It was found that in the system Mn(OOCCH3)2-Zn(OOCCH3)2-H2O crystallizes Zn(OOCCH3)2 · Mn(OOCCH3)2 · 2 H2O. It was identified by the X-ray and differential thermal analysis. |
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