Abstract: | The many-body Green's function method is applied to the vertical ionization potential of the hydrogen molecule. The ionization potential is calculated iteratively by expanding the self-energy part up to third order. The effects of higher-order correlation corrections and nondiagonal self-energy elements on the solutions of the Dyson equation are examined with some techniques and approximations, by means of which a Koopmans' defect of 97.7% of the accurate value is obtained. |