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Reaction of benzoyl and trichloroacetyl isocyanates with cyclic enamines
Authors:B A Arbuzov  N N Zobova  F B Balabanova
Institution:(1) V. I. Ul'yanov-Lenin Kazan State University, USSR
Abstract:Conclusions Benzoyl isocyanate reacts with morpholinocyclohexene, morpholinocyclopentene, piperidinocyclohexene, and piperidinocyclopentene on the type of 1,4-cycloaddition, with the formation of 1,3-oxazin-4-one derivatives, while trichloroacetyl isocyanate reacts on the type of 1,2-cycloaddition, with the formation of 2-azetidinone derivatives, and only with morpholinocyclopentene does it react on the type of 1,4-cycloaddition.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2086–2088, September, 1972.
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