Carbon-carbon bond construction on solid support: triethylborane-induced radical reactions of oxime ethers |
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| Authors: | Hideto MiyabeAzusa Nishimura Yumi FujishimaTakeaki Naito |
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| Institution: | Kobe Pharmaceutical University, Motoyamakita, Higashinada, Kobe 658-8558, Japan |
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| Abstract: | The triethylborane-induced solid-phase radical reaction was studied. The solid-phase radical reaction of oxime ether anchored to Wang resin proceeded smoothly to give the α-amino acid derivatives. The carbon-carbon bond-forming radical reaction of TentaGel OH resin-bound glyoxylic oxime ether proceeded even in aqueous media. |
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| Keywords: | radical reactions solid-phase reactions amino acids oxime ethers |
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