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Quaternized amino functionalized cross-linked polyacrylamide as a new solid-liquid phase transfer catalyst in reduction of carbonyl compounds with NaBH4
Authors:Bahman Tamami  Hossein Mahdavi
Institution:Department of Chemistry, Shiraz University, Adabiat av., Shiraz 71454, Iran
Abstract:PolyN-(2-aminoethyl)acrylamido]trimethyl ammonium chloride resin was developed as a new polymeric phase transfer catalyst. This quaternized polyacrylamide catalyzed the chemoselective reduction of aldehydes and ketones by NaBH4 to give corresponding alcohols in high yields under mild conditions.
Keywords:polyacrylamide  NaBH4  poly[N-(2-aminoethyl)acrylamide]
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