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Diastereoselective synthesis of β-substituted α-hydroxyphosphinates through hydrophosphinylation of α-heteroatom-substituted aldehydes |
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| Authors: | Takehiro YamagishiTakanori Kusano Babak KaboudinTsutomu Yokomatsu Chiseko SakumaShiroshi Shibuya |
| Institution: | a School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan b Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Gava Zang, Zanjan 45195-159, Iran |
| Abstract: | The diastereoselective synthesis of β-substituted α-hydroxyphosphinates was achieved by hydrophosphinylation of α-oxy aldehydes and α-amino aldehydes with ethyl allylphosphinate catalyzed by lithium phenoxide. |
| Keywords: | diastereoselection phosphinic acids and derivatives |
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