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Ionic liquid as an efficient promoting medium for two-phase nucleophilic displacement reactions
Authors:Nuno MT LourençoCarlos AM Afonso
Abstract:The use of the room temperature ionic liquid (RTIL) 1-n-butyl-3-methylimidazolium hexafluorophosphate as an efficient catalyst and solvent for several representative nucleophilic substitution reactions under aqueous-RTIL phase transfer conditions was explored. Recycling and reuse of the reaction medium was demonstrated for the azide formation.
Keywords:ionic liquids  nucleophilic substitution  Schiff base  aryl alkyl ether  alkyl iodide  alkyl cyanide  alkyl azide  recycling
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