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A selective method for the determination of benzo[a]pyrene in soil using porous graphitic carbon liquid chromatography columns
Authors:Al-Haddad Ameera
Institution:Department of Chemistry, University of Bahrain, P.O. Box 32038, Isa Town, Bahrain
Abstract:A back-flushing procedure using porous graphitic carbon (PGC) HPLC columns has been used successfully for the cleanup of soil samples for the determination of benzoa]pyrene in ppb levels by an ODS-fluorescence HPLC column. The procedure was tested on nine random soil samples taken from an industrial area of the Kingdom of Bahrain. The mean percent recovery from the PGC column was 96% and the average coefficient of variation for the whole method was 5.2%.
Keywords:Benzo[a]pyrene  Porous graphitic carbon  Soil analysis  Polycyclic aromatic hydrocarbons
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