Evaluation of the Effect of the Furazane Fragment on the NH Acidity of 4- and 5-Picrylaminobenzofurazanes in DMF and DMSO |
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Authors: | F. S. Levinson S. A. Akimova E. A. Ermolaeva B. I. Khairutdinov M. I. Evgen’ev |
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Affiliation: | (1) Kazan State Technological University, Kazan, Tatarstan, Russia;(2) Kazan State University, Kazan, Tatarstan, Russia |
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Abstract: | The products of the reactions of picryl chloride with isomeric aminobenzofurazanes in DMF and DMSO were studied by means of nonaquoeus potentiometric titration. The effect of the position of the furazane fragment in 4- and 5-picrylaminobenzofurazanes on the NH acidity is considered. The electron-acceptor properties of the furazane fragment were evaluated via inclusion of the resulting data into the pKa-σ correlation for 2,4,6-trinitrodiphenylamines. On this basis, conventional Hammett σ constants were calculated for the furazane fragment located in the immediate vicinity of the N-H center and one position distant from it.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 6, 2005, pp. 988–990.(-10V)Original Russian Text Copyright © 2005 by Levinson, Akimova, Ermolaeva, Khairutdinov, Evgen’ev. |
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