GaCl3-catalyzed insertion of isocyanides into a C-O bond in cyclic ketals and acetals |
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| Authors: | Yoshioka Sachiko Oshita Masayuki Tobisu Mamoru Chatani Naoto |
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| Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. |
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| Abstract: | The reaction of cyclic ketals or acetals with 2,6-dibromophenylisocyanide in the presence of a catalytic amount of GaCl(3) results in the insertion of isocyanide into the carbon-oxygen bond of cyclic ketals and acetals. [reaction: see text] |
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