Synthesis of some zerovalent complexes of iron via aryldiazenato cationic complexes |
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| Authors: | S. Vancheesan |
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| Affiliation: | (1) Department of Chemistry, Indian Institute of Technology, 600 036 Madras, India |
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| Abstract: | Bis (triphenylphosphine) dicarbonylaryldiazenato-iron, [Fe0 (ArN2) (CO)2 (PPhs)2]+(I), reacts in a solution of LiOEt under nitrogen atmosphere, with a variety of group V donor ligands, substituting the aryldiazenato ligand, ArN2+. The effect of substitution on the stretching frequency of CO is discussed. |
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| Keywords: | Aryldiazenato cationic complex substitution reactions zero-valent complexes iron |
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