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Mössbauer studies of Jarosite, Mikasaite and Yavapaiite, and implication to their Martian counterparts
Authors:Kiyoshi Nomura  Masuo Takeda  Takeshi Iiyama  Hitoshi Sakai
Institution:(1) School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku Tokyo, 113-8656, Japan;(2) Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi Chiba, 274-8510, Japan;(3) Okayama University, Okayama, Japan
Abstract:In order to confirm Mössbauer spectra of Jarosite, unidentified Fe3+ species (Fe3D3) and Fe2O3 found on Martian surface, some Jarosite specimens produced on Earth were characterized by 57Fe Mössbauer spectroscopy. For comparison, anhydrous ferric sulfate minerals, Mikasaite (Fe3+ 1.56Al0.44)(SO4)3, and Yavapaiite, KFe (SO4)2 were also measured. The thermal decomposition products of Jarosite and their hydration products were also traced by scattering Mössbauer spectra (CEMS and XMS). These data are useful for the identification of hydrous and anhydrous ferric sulfate phases on Mars, including Fe3D3.
Keywords:M?ssbauer spectra  CEMS  XMS  Jarosite  thermal decomposition  hydration  Mars
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