| 杂原子ZSM-48型分子筛研究 III. 杂原子存在状态 |
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| 引用本文： | 焦庆祝,庞文琴.杂原子ZSM-48型分子筛研究 III. 杂原子存在状态[J].物理化学学报,1991,7(6):662-665. |
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| 作者姓名： | 焦庆祝 庞文琴 |
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| 作者单位： | Institute of Synthetic and Catalytic Chemistry of Jilin University 130023 |
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| 摘 要： | X射线衍射、红外光谱、X射线光电子能谱、磁化率、电子自旋共振等研究结果表明, 杂原子以畸变四面体配位方式占据M-ZSM-48(M=B、Cr、Ge、V)型分子筛骨架, V、Cr分别以V(Ⅳ)和Cr(Ⅲ)形式存在。
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| 关 键 词： | 杂原子 ZSM-48 结构 |
| 收稿时间： | 1990-06-11 |
| 修稿时间： | 1990-11-28 |
Studies on Hetero-Atom ZSM-48 Type Molecular Sieves III. Existing State of Hetero-atom |
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| Jiao Qingzhu Pang Wenqin.Studies on Hetero-Atom ZSM-48 Type Molecular Sieves III. Existing State of Hetero-atom[J].Acta Physico-Chimica Sinica,1991,7(6):662-665. |
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| Authors: | Jiao Qingzhu Pang Wenqin |
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| Institution: | Institute of Synthetic and Catalytic Chemistry of Jilin University 130023 |
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| Abstract: | It was identified by many techniques such as XRD, IR, XPS, ESR and magnetic susceptibility measurement that the hetero-atoms on the frameworks of M-ZSM-48 type molecular sieves reside at the sites of distorted tetrahedral coordination. V and Cr exist as V(Ⅳ) and Cr(Ⅲ) respectively. |
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| Keywords: | Hetero-atom ZSM-48 Structure |
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