| 对位取代四苯基卟啉铜(II)的生成动力学及其它金属离子的影响 |
| |
| 引用本文： | 朱志昂,夏新,陈荣悌.对位取代四苯基卟啉铜(II)的生成动力学及其它金属离子的影响[J].物理化学学报,1991,7(4):456-461. |
| |
| 作者姓名： | 朱志昂 夏新 陈荣悌 |
| |
| 作者单位： | Department of Chemistry, Nankai University, Tianjin 300071 |
| |
| 摘 要： | 本文用Shimadzu UV-240紫外可见分光光度计对Cu(Ⅱ)与对位取代四苯基卟啉H_2(p-X)TPP(X=NO_2, (Cl,H,CH_3,OCH_3)在二甲亚砜溶剂中的生成动力学及镉(Ⅱ)离子对该反应的催化作用进行了系统研究, 提出了反应机理, 并观察了Hg(Ⅱ)、Pb(Ⅱ)等其它金属离子对此反应的影响。发现反应速率常数及平衡常数与Hammett取代常数σ值之间呈现良好的直线自由能关系。
|
| 关 键 词： | 对位取代四苯基卟啉铜(II) 生成动力学 机理 |
| 收稿时间： | 1990-03-10 |
| 修稿时间： | 1991-02-01 |
Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions |
| |
| Zhu Zhi-Ang,Xia Xin,Chen Rong-Ti.Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions[J].Acta Physico-Chimica Sinica,1991,7(4):456-461. |
| |
| Authors: | Zhu Zhi-Ang Xia Xin Chen Rong-Ti |
| |
| Institution: | Department of Chemistry, Nankai University, Tianjin 300071 |
| |
| Abstract: | The kinetics of formation reaction of Copper(Ⅱ) with para-substituted tetraphenylporphyrin H_2(p-X)TPP (X=NO_2,Cl,H, CH_3,OCH_3) in dimethyl sulfoxide solution and the catalytic effect of Cadmium(Ⅱ) ion have been studied on Shimadru UV-240 spectrophotometer. The mechanisms were proposed and the effect of Hg(Ⅱ), Pb(Ⅱ) on this reaction was investigated. Good LFER (linear free energy relationahips) between reaction rate constant/equilibrium constant with the Hammett subtituent constant σ have been ob served in certain cases. |
| |
| Keywords: | (Para-substituted tetraphenylporphinato)-Copper(II) Kinetics of formation Mechanisms |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
|
