| 稀有气体亚稳态原子与CCl4和CBr4的能量转移反应 |
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| 引用本文： | 郭敬忠,顾月姝,刘传朴,印永嘉,曹德兆,廖常焕. 稀有气体亚稳态原子与CCl4和CBr4的能量转移反应[J]. 物理化学学报, 1991, 7(2): 207-210. DOI: 10.3866/PKU.WHXB19910215 |
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| 作者姓名： | 郭敬忠 顾月姝 刘传朴 印永嘉 曹德兆 廖常焕 |
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| 作者单位： | Chemistry Department, Shandong University, Jinan 250100; Anhui Institute of Optics and Fine Mechanics |
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| 摘 要： | CBr_4和CCl_4分子的解离反应前人已做了许多工作,他们分别采用射频放电、电子轰击、He~ 的传能反应等方法研究了CCl_4和CBr_4的解离反应,得到了CCI(A)、CCl~ 、CBr~ 等碎片的发射光谱。有关亚稳态原子与它们的传能反应,只有某些较简单的报道,对传能反应机理也未作深入探讨。本文研究了各种亚稳态原子He(2~3S)、Ne(~3P_(0.2))、Ar(~3P_(0.2))与CCl_4和CBr_4分子的传能反应,并对反应机理进行了初步的讨论和分析。
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| 关 键 词： | 稀有气体 CCl4 CBr4 亚稳态原子反应 能量转移过程 |
| 收稿时间： | 1989-09-04 |
| 修稿时间： | 1990-04-10 |
ENERGY TRANSFER PROCESSES IN REACTION BETWEEN METASTABLE ATOMS Ar, He AND Ne WITH CCl_4 and CBr_4 |
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| Guo Jingzhong Gu Yuezhu Liu Chuanpu Yin Yongjia. ENERGY TRANSFER PROCESSES IN REACTION BETWEEN METASTABLE ATOMS Ar, He AND Ne WITH CCl_4 and CBr_4[J]. Acta Physico-Chimica Sinica, 1991, 7(2): 207-210. DOI: 10.3866/PKU.WHXB19910215 |
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| Authors: | Guo Jingzhong Gu Yuezhu Liu Chuanpu Yin Yongjia |
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| Affiliation: | Chemistry Department, Shandong University, Jinan 250100; Anhui Institute of Optics and Fine Mechanics |
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| Abstract: | In this paper we used the flowing-afterglow technique to study the energy transfer processes in the reaction of metastable atoms Ar, Ne, and He with CCl_4 and CBr_4, The emission spectra of excited fragments CCl (A—X), Cl_2~* and Br_2~* were obtained. The reaction mechanism were discussed. |
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| Keywords: | Ar He Ne CCl_4 CBr_4 Reaction of metastable atom Energy transfer processes |
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