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He(23S)与含氢卤代甲烷传能反应中产生的CH(A2Δ,ν'=0)的新生态转动分布
引用本文:郭敬忠,顾月姝,刘传朴,李保中,印永嘉,蔡继业,曹德兆.He(23S)与含氢卤代甲烷传能反应中产生的CH(A2Δ,ν'=0)的新生态转动分布[J].物理化学学报,1991,7(2):211-214.
作者姓名:郭敬忠  顾月姝  刘传朴  李保中  印永嘉  蔡继业  曹德兆
作者单位:Chemistry Department, Xiamen University, Xiamen 361005; Physics Department, Xiamen University
摘    要:

关 键 词:He  卤代甲烷  转动分布  
收稿时间:1989-09-04
修稿时间:1990-04-10

Study on the Structure Defect of Electrodeposited Tin Using Positron Annihilation Lifetime Spectroscopy
Guo Jing-Zhong,Gu Yue-Shu,Liu Chuan-Pu,Li Bao-Zhong,Yin Yong-Jia,Cai Ji-Ye,Cao De-Zhao.Study on the Structure Defect of Electrodeposited Tin Using Positron Annihilation Lifetime Spectroscopy[J].Acta Physico-Chimica Sinica,1991,7(2):211-214.
Authors:Guo Jing-Zhong  Gu Yue-Shu  Liu Chuan-Pu  Li Bao-Zhong  Yin Yong-Jia  Cai Ji-Ye  Cao De-Zhao
Institution:Chemistry Department, Xiamen University, Xiamen 361005; Physics Department, Xiamen University
Abstract:The excited fragments CH(A), CH(B), CH(C) etc. were produced by the bombardment of He(2~3S) with CH_nX_(4-n)(X=Cl, Br, I). Based on the CH(A-X) emission spectra, the rotational populations can be interpretated in terms of Boltzmann distribution. The effective rotational temperature for CH(A,v'=0) produced from various methyl halides are nearly the some. Experiments under various pressure and calculation of collisional dynamics showed that the distributions are approximate to the nascent distributions.
Keywords:He'  ')  He" target="_blank">">He  Methyl halides  '  ')  Rotational distribution" target="_blank">">Rotational distribution
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