| 氧化铅@碳纳米复合材料的制备与表征 |
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| 引用本文： | 王慧奇,丁国荣,赵永男,余建国. 氧化铅@碳纳米复合材料的制备与表征[J]. 高等学校化学学报, 2009, 30(7): 1287-1289 |
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| 作者姓名： | 王慧奇 丁国荣 赵永男 余建国 |
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| 作者单位： | 天津工业大学纳米结构材料研究所,天津市改性与功能纤维重点实验室,天津,300160;中国石油吉林石化公司研究院,吉林,132021 |
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| 摘 要： | 以淀粉为碳源, 高温碳化含有硝酸铅的淀粉干凝胶, 制备了氧化铅@碳纳米复合材料,氧化铅颗粒无团聚, 粒径可调, 近于单分散, 且分布均匀, 可作为铅酸电池的电极材料, 有望提高其充放电性能和使用寿命.
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| 关 键 词： | 淀粉 碳化 氧化铅 纳米复合材料 |
| 收稿时间： | 2009-03-10 |
Preparation and Characterization of PbO@C Nanocomposites |
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| WANG Hui-Qi,DING Guo-Rong,ZHAO Yong-Nan,YU Jian-Guo. Preparation and Characterization of PbO@C Nanocomposites[J]. Chemical Research In Chinese Universities, 2009, 30(7): 1287-1289 |
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| Authors: | WANG Hui-Qi DING Guo-Rong ZHAO Yong-Nan YU Jian-Guo |
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| Affiliation: | 1. Institute of Nanostructured Materials, Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, China;2. Research Institute of Petrochina Jilin Petrochemical Company, Jilin 132021, China |
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| Abstract: | Lead oxide nanoparticles embedded carbon composites have been fabricated via the pyrolysis of Pb(NO3)2 impregnated starch gel under a N2 gas flow. The products were characterized by XRD, TGA, and TEM. The mass ratio between starch and Pb(NO3)2 greatly affected the final produts. The particle sizes of PbO decreased with the content of starch increased in the starting gel. Gel with mass ratio of 85∶15 between starch and Pb(NO3)2 gave rise to well-dispered lead oxide nanoparticles with tubable size and narrow size distribution that embedded in the carbon matrix. The particle sizes were in the range of 9—15 nm. Varying the reaction temperature would change the form of lead oxide. Lead oxide in the products calcined at 1000 ℃ was mainly β-PbO. |
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| Keywords: | Starch Carbonization Lead oxide Nanocomposites |
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