|
|||||
|
|
Reactions of cage metal siloxanes with functionalized organochlorosilanes |
|
| Authors: | Makarova L I Sergienko N V Trankina E S Zhdanov A A Ahmet"eva E A |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) Karpov Institute of Physical Chemistry, Russian Federal Research Center, 10 ul. Vorontsovo pole, 103064 Moscow, Russian Federation |
| Abstract: | The reactions of (2-acetoxyetoxy)methyl]dimethylchlorosilane and 1-acetoxy-2-(dimethylchlorosilylmethoxy)benzene with the cage phenylcopper and phenylmanganese siloxanes leads to the cleavage of the M—O—Si bond to give metal chlorides and six-unit cyclosiloxanes with an acetoxy group in the organic substituent at the silicon atom. Methanolysis of these acetoxy derivatives does not affect the ring structure and affords the corresponding polyhydric alcohols. |
| Keywords: | cage metal siloxanes organochlorosilanes organocyclosiloxanes with functional groups in the organic substituents at silicon |
| 本文献已被 SpringerLink 等数据库收录！ | |