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Stabilization in the order I>Br>Cl among trimethylsilylmethyl halides,compared to carbon analogs. Possible role of electronegativity in organosilicon chemistry
Authors:Paul E Peterson
Institution:Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208 U.S.A.
Abstract:Electronegativities may be used to rationalize the observation that the equilibrium, CH3(CH2)3I + (CH3)3SiCH2Cl ? CH3(CH2)3Cl + (CH3)3SiCH2I, lies to the right.
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