Stabilization in the order I>Br>Cl among trimethylsilylmethyl halides,compared to carbon analogs. Possible role of electronegativity in organosilicon chemistry |
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Authors: | Paul E Peterson |
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Institution: | Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208 U.S.A. |
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Abstract: | Electronegativities may be used to rationalize the observation that the equilibrium, CH3(CH2)3I + (CH3)3SiCH2Cl ? CH3(CH2)3Cl + (CH3)3SiCH2I, lies to the right. |
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