Photocycloreversion-reaction of a cage molecule and related cyclobutanes with cationic sensitizers |
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Authors: | Keiji Okada Kunio Hisamitsu Toshio Mukai |
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Institution: | Photochemical Research Laboratory, Faculty of Science, Tohoku University Aramaki, Sendai 980 Japan |
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Abstract: | Irradiation of 1, 2, or 3 in acetonitrile in the presence of cationic sensitizer 7 or 8 afforded the cycloreversion product 4, 5 or 6, respectively. A wide range in quantum yields were found and these were dependent on the substrates and sensitizers. |
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