The rearrangement of some 2-substituted-4-bromo-2,5-dinitro-6-hydroxy-3,6-dimethylcyclohex-3-en-1-ones |
| |
| Authors: | PA Bates MJ Gray MP Hartshorn Huong Tuong Ing KE Richards WT Robinson |
| |
| Institution: | Chemistry Department, University of Canterbury, Christchurch, New Zealand |
| |
| Abstract: | In chloroform at 20°, or in tetrachloroethylene at 120°, the title compounds (1) rearrange to give the α-diketone(2), the structure of which was determined by X-ray crystal structure analysis; a possible rearrangement mechanism is outlined. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
