Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines |
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| Authors: | Cadierno Victorio García-Garrido Sergio E Gimeno José Nebra Noel |
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| Institution: | Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles (Unidad Asociada al C.S.I.C.), Universidad de Oviedo, 33071, Oviedo, Spain. vcm@uniovi.es |
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| Abstract: | A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes Ru(eta3:eta2:eta3-C12H18)Cl2] and {Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2], has been developed. |
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