| 氨基喹啉水杨醛Schiff碱配合物的合成、晶体结构及抑菌性能 |
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| 引用本文： | 史娟,李江,葛红光. 氨基喹啉水杨醛Schiff碱配合物的合成、晶体结构及抑菌性能[J]. 无机化学学报, 2017, 33(3): 463-470 |
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| 作者姓名： | 史娟 李江 葛红光 |
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| 作者单位： | 陕西理工大学化学与环境科学学院, 陕西省催化基础与应用重点实验室, 汉中 723000,陕西理工大学化学与环境科学学院, 陕西省催化基础与应用重点实验室, 汉中 723000,陕西理工大学化学与环境科学学院, 陕西省催化基础与应用重点实验室, 汉中 723000 |
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| 基金项目： | 国家自然科学基金（No.21373132）、陕西省教育厅专项科研基金（No.15JK1141）和陕西省自然科学基金（No.2015JM2060）资助项目。 |
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| 摘 要： | 经缩合反应制备了4-甲氧基水杨醛缩-6-氨基喹啉希夫碱配体(L),并采用溶剂热法使其与Co(Ⅱ)、Zn(Ⅱ)和Cu(Ⅱ)三种金属离子进行配位得到配合物[Co L2](1),[ZnL_2](2)及[Cu L2](3),所得化合物结构通过元素分析、红外光谱、核磁共振谱及X射线单晶衍射法进行表征。生物测试结果表明,配体(L)及配合物1~3对马铃薯干腐病菌、苹果炭疽病菌、苹果腐烂病菌、番茄灰霉病菌4种植物病原菌具有较好的抑菌活性。
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| 关 键 词： | 6-氨基喹啉水杨醛希夫碱 配合物 晶体结构 生物活性 |
| 收稿时间： | 2016-10-25 |
| 修稿时间： | 2016-12-08 |
Syntheses, Crystal Structures and Antibacterial Activities of Complexes with N-(6-Quinolyl) salicylaldimine Ligand |
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| SHI Juan,LI Jiang and GE Hong-Guang. Syntheses, Crystal Structures and Antibacterial Activities of Complexes with N-(6-Quinolyl) salicylaldimine Ligand[J]. Chinese Journal of Inorganic Chemistry, 2017, 33(3): 463-470 |
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| Authors: | SHI Juan LI Jiang GE Hong-Guang |
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| Affiliation: | Shaanxi Key Laboratory of Catalysis, School of Chemical and Environmental Sciences, Shaanxi Sci-Tech University, HanZhong, Shaanxi 723001, China,Shaanxi Key Laboratory of Catalysis, School of Chemical and Environmental Sciences, Shaanxi Sci-Tech University, HanZhong, Shaanxi 723001, China and Shaanxi Key Laboratory of Catalysis, School of Chemical and Environmental Sciences, Shaanxi Sci-Tech University, HanZhong, Shaanxi 723001, China |
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| Abstract: | The 4-methoxy-6-amine quinolone Schiff base (L) was prepared, and[CoL2] (1),[ZnL2] (2) and[CuL2] (3) complexes were synthesized. The structures of compounds were characterized by IR, 1H NMR, elemental analysis and X-ray single crystal diffraction. Their biological test results showed that they exhibited good fungicidal activities to four vegetable pathogens (Fusarium solani, Colletotrichum gloeosporioides, Cytospora sp. and Botrytis cinerea). CCDC:1508993, L; 1508994, 1; 1508995, 2. |
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| Keywords: | N-(6-quinolyl)salicylaldimine ligand complex crystal structure antibacterial activity |
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