Lanthanide(III) 2-naphthoxide complexes stabilized by interligand non-covalent interactions |
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| Authors: | Levin Jessica R Gu Jun Carroll Patrick J Schelter Eric J |
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| Institution: | P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA. |
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| Abstract: | Lithium-lanthanide-2-naphthoxide complexes are found to have solvent dependent solution structures and related monomeric/dimeric solid state structures. The incorporation of tetramethylguanidium cations into lanthanide 2-naphthoxide complexes stabilizes a complex structure both in solution and the solid state through bridging hydrogen bonds between the 2-naphthoxide ligands. |
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