| 3-硝基邻苯二甲腈的合成 |
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| 引用本文： | 陈志敏,左霞,吴谊群,陈耐生.3-硝基邻苯二甲腈的合成[J].合成化学,2004,12(2):167-169,173. |
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| 作者姓名： | 陈志敏 左霞 吴谊群 陈耐生 |
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| 作者单位： | 黑龙江大学化学化工学院,功能材料实验室,黑龙江,哈尔滨,150080;福州大学功能材料研究所,化学化工学院,福建,福州,350002 |
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| 基金项目： | 黑龙江省自然科学基金资助项目 (B0 1 0 7) |
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| 摘 要： | 以邻苯二甲酸酐为原料，经过硝化、脱水、亚胺化、氨解、脱水5步反应，高产率地合成了3-硝基邻苯二甲腈，研究了邻苯二甲酸酐的硝化反应、3-硝基邻苯二甲酰胺的脱水条件对产率的影响。目标化合物的结构用元素分析，IR和^1H NMR表征。
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| 关 键 词： | 金属酞菁 3-硝基邻苯二甲腈 合成 中间体 |
| 文章编号： | 1005-1511(2004)02-0167-03 |
Synthesis of 3-Nitrophthalonitrile |
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| CHEN Zhi-min ,ZUO Xia ,WU Yi-qun ,CHEN Nai-sheng.Synthesis of 3-Nitrophthalonitrile[J].Chinese Journal of Synthetic Chemistry,2004,12(2):167-169,173. |
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| Authors: | CHEN Zhi-min ZUO Xia WU Yi-qun CHEN Nai-sheng |
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| Institution: | CHEN Zhi-min 1,ZUO Xia 1,WU Yi-qun 1,CHEN Nai-sheng 2 |
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| Abstract: | 3-Nitrophthalonitrile was synthesized in a higher yield from phthalic anhydride through 5 steps: nitration, dehydration, ammoiation, aminolysis and dehydration and the products were confirmed by elemental analysis, IR and 1H NMR. The effects of reaction conditions of two steps, nitration of phthalic anhydride and dehydration of 3-nitrophthalamide, were studied. |
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| Keywords: | metal phthalocyanine 3-nitrophthalonitrile synthesis intermediate |
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