Regiochemistry of Cleavage of Monosubstituted Oxiranes by Phosphorochloridites. Enantiomeric Composition of Oxiranes by 31P NMR Spectral Data |
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| Authors: | Bredikhina Z A Novikova V G Azancheev N M Bredikhin A A |
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| Institution: | (1) Arbuzov Institute of Organic Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
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| Abstract: | The regioisomeric composition of the adducts of unsymmetrical oxiranes with achiral and chiral phosphorochloridites was studied. Factors allowing enantiomeric assessment of chiral oxiranes with the aid of chiral derivatizing organophosphorus reagents were revealed. |
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