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Effect of Cu addition on whisker formation in tin-rich solder alloys under thermal shock stress
Authors:A. Skwarek  J. Ratajczak  K. Witek
Affiliation:a Department of Microelectronics, Institute of Electron Technology, Zablocie 39, 30-701 Cracow, Poland
b Department of Materials and Semiconductor Structures Research, Institute of Electron Technology, Al. Lotnikow 32/46, 02-668 Warsaw, Poland
c Department of Implementation and Production, Institute of Electron Technology, Zablocie 39, 30-701 Cracow, Poland
Abstract:This article focuses on the influence of thermal shocks and Cu addition on tin whiskers growth on the surface of tin-rich materials and alloys. The tests were carried out on real samples manufactured with classical PCB technology. Four Pb-free materials i.e. pure Sn, Sn99Cu1, Sn98Cu2 and Sn97Cu3 were tested from the point of view of susceptibility to whisker formation after thermal shocks. Results show that all tested materials were prone for whisker formation. Copper addition in coexistence with thermal shocks did not promote the growth of filament-like whiskers.
Keywords:Pb-free alloys   Whiskers   SEM   Thermal shocks
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