High-order perturbed corrections with scaling transformation |
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Authors: | Zhao Yun-Hui and Zhao Cheng-Lin |
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Institution: | epartment of Physics, Shaoyang University,
Shaoyang 422000,
China; epartment of Physics, Shaoyang University,
Shaoyang 422000,
China;Department of Physics, Hunan Normal University, Changsha
410081, China |
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Abstract: | The performance of the so-called superconvergent quantum
perturbation theory (Wenhua Hai {\em et al} 2000 \emph{Phys. Rev.} A
{\bf 61} 052105) is investigated for the case of the ground-state
energy of the helium-like ions. The scaling transformation
$r\rightarrow r/Z$ applied to the Hamiltonian of a two-electron
atomic ion with a nuclear charge $Z$ (in atomic units). Using the
improved Rayleigh--Schr\"{o}dinger perturbation theory based on
the integral equation to helium-like ions in the ground states and
treating the electron correlations as perturbations, we have
performed a third-order perturbation calculation and obtained the
second-order corrected wavefunctions consisting of a few terms and
third-order energy corrections. We find that third-order and
higher-order energy corrections are improved with decreasing nuclear
charge. This result means that the former is quadratically
integrable and the latter is physically meaningful. The improved
quantum perturbation theory fits the higher-order perturbation case.
This work shows that it is a development on the quantum perturbation
problem of helium-like systems. |
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Keywords: | integral equation scaling
transformation higher-order perturbation |
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