8-Methoxy-5-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalene: synthesis and reactivity |
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| Authors: | A. F. Asachenko V. V. Izmer A. V. Babkin I. P. Beletskaya A. Z. Voskoboynikov |
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| Affiliation: | 1.Department of Chemistry,M. V. Lomonosov Moscow State University,Moscow,Russian Federation |
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| Abstract: | ![]()
A new single-step approach to cyclopenta[a]naphthalenes through TiCl4-catalyzed reactions of 1-trimethylsilyloxycyclopentene with arylacetaldehydes was proposed. 8-Methoxy-5-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalene and its derivatives were studied in oxidation and bromination reactions, as well as in hydrolytic cleavage of the O-Me bond. |
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