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Reaction of unsaturated sulfoxides with alkyllithiums |
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| Authors: | Günter Neef Ulrich Eder Arne Seeger |
| Affiliation: | Research Laboratories, schering AG Berlin/Bergkamen, Müllerstraβe 170–178, D-1000 Berlin 65, West-Germany. |
| Abstract: | Nucleophilic attack of methyllithium on allene sulfoxides offers a stereospecific access to sulfur-free allenes. Reaction of phenylsulfinyl substituted diene leads via a benzilic-type rearrangement to phenyl substituted diene . |
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