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Convenient synthesis of β,γ-unsaturated γ-dithiolactones from allenylsilver(I) compounds |
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| Authors: | H. Westmijze K. Ruitenberg J. Meijer P. Vermeer |
| Affiliation: | Department of Organic Chemistry of the University, Croesestraat 79, 3522 AD Utrecht, The Netherlands |
| Abstract: | Allenylsilver(I) compounds react with carbon disulfide to silver(I) 3-alkynedithioates; β,γ-unsaturated γ-dithiolactones are formed by spontaneous cyclisation of these dithioates. |
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