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The reaction of hypochlorous acid with olefins. A convenient synthesis of allylic chlorides |
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| Authors: | Shridhar G. Hegde Martin K. Vogel John Saddler Tanya Hrinyo Ned Rockwell Robert Haynes Michael Oliver Joseph Wolinsky |
| Affiliation: | Department of Chemistry, Purdue University, West Lafayette, Indiana 47907 U.S.A. |
| Abstract: | The reaction of HOCl with more highly substituted olefins in methylene chloride affords allylic chlorides in 60–80% isolated yields. The utility of the reaction is illustrated with the synthesis of Rose oxide and α-monoterpenes. |
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