Deoxygenation of allylic alcohols to terminal olefins via stannylation/destannylation |
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| Authors: | Yoshio Ueno Hiroshi Sano Makoto Okawara |
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| Institution: | Laboratory of Resources Utilization, Tokyo Institute of Technology, Nagatsuta 4259, Midori-ku, Yokohama 227, Japan |
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| Abstract: | Deoxygenation of allylic alcohols to terminal olefins was performed via three steps; 1) 3,3]-sigmatropic rearrangement of O-allylxanthates, 2) the successive stannolysis with tributyltin hydride yielding allylic stannanes, and 3) final protolysis of allylic stannanes to terminal olefins. |
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