Competing cheletropic reactions of difluorocarbene with various 2-substituted norbornadienes |
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| Authors: | Charles W Jefford Phan Thanh Huy |
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| Institution: | Department of Organic Chemistry, University of Geneva, 1211 Geneva 4, Switzerland |
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| Abstract: | Norbornadienes substituted at C2 with electron donating, conjugating, and withdrawing groups react with difluorocarbene to give a ratio of 1,2 to homo-1,4 adducts, which reflects a diminishing response of electrophilic character in the carbene. |
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