The direct photo-oxidative decarboxylation of α-oxo-carboxylic acids |
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Authors: | R Stephen Davidson Dean Goodwin Geoffrey Turnock |
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Institution: | Department of Chemistry, The City University, Northampton Square, London EC1V 0HB U.K.;Department of Biochemistry, University of Leicester, Leicester, LE1 7RH England |
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Abstract: | α-Oxo-carboxylic acids undergo photo-oxidative decarboxylation from both C-1 and C-2 positions, and reaction does not involve singlet oxygen: a mechanism involving an electron transfer reaction is postulated. |
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