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The direct photo-oxidative decarboxylation of α-oxo-carboxylic acids
Authors:R Stephen Davidson  Dean Goodwin  Geoffrey Turnock
Institution:Department of Chemistry, The City University, Northampton Square, London EC1V 0HB U.K.;Department of Biochemistry, University of Leicester, Leicester, LE1 7RH England
Abstract:α-Oxo-carboxylic acids undergo photo-oxidative decarboxylation from both C-1 and C-2 positions, and reaction does not involve singlet oxygen: a mechanism involving an electron transfer reaction is postulated.
Keywords:
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