The mechanism of the singlet oxygen ene reaction |
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| Authors: | LM Stephenson |
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| Institution: | Department of Chemistry and Hydrocarbon Research Institute University of Southern California Los Angels, California 90007 U.S.A. |
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| Abstract: | A complex between singlet oxygen and olefins is proposed in which frontier orbital interactions between the oxygen and both the olefin π orbitals and C-H bonds are important. Formation of this complex is proposed to dominate the chemistry of this reaction and is shown to be consistent with the available data. |
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