Base catalyzed rearrangement of some bicyclic ketol acetates. |
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Authors: | M. Kalyanasundaram K. Rajagopalan S. Swaminathan |
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Affiliation: | Department of Organic Chemistry, University of Madras, A.C. College Campus, Madras-600 025, India. |
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Abstract: | The ketol and its acetate when refluxed in methanolic potassium hydroxide (5%) were found to rearrange to 4-methyl-8-acetyl-5,6,7,8-tetrahydro-1-naphthol . The epimeric acetate also behaved likewise. A mechanism is suggested for the rearrangement. |
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Keywords: | To whom all correspondence should be made. |
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