首页 | 本学科首页   官方微博 | 高级检索  
     


Base catalyzed rearrangement of some bicyclic ketol acetates.
Authors:M. Kalyanasundaram  K. Rajagopalan  S. Swaminathan
Affiliation:Department of Organic Chemistry, University of Madras, A.C. College Campus, Madras-600 025, India.
Abstract:The ketol 3a and its acetate 3b when refluxed in methanolic potassium hydroxide (5%) were found to rearrange to 4-methyl-8-acetyl-5,6,7,8-tetrahydro-1-naphthol 4. The epimeric acetate 3c also behaved likewise. A mechanism is suggested for the rearrangement.
Keywords:To whom all correspondence should be made.
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号