Stereoelectronic control in the oxidation of gem-disulphides |
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| Authors: | M Poje M Sikirica I Vicković M Bruvo |
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| Affiliation: | Department of Organic Chemistry and Biochemistry, Faculty of Science, University of Zagreb, Strossmayerov trg 14, 41000 Zagreb, Yugoslavia;Laboratory of General and Inorganic Chemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, P. O. Box 153, Yugoslavia |
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| Abstract: | The first example of stereospecific oxidation in the gem-disulphide series is reported; chemical, spectral, and X-ray evidence indicated the stereoelectronic discrimination between two modes of approach of electrophile in the conversion to meso-2,2-bis(methylsulphinyl)-1,3-diphenylpropane (). |
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