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Cp2TiCl2-catalyzed grignard reactions. 2. Reactions with ketones and aldehydes
Authors:Fumie Sato  Takamasa Jinbo  Masao Sato
Institution:Department of Chemical Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan
Abstract:The reaction of Grignard reagents with ketones or aldehydes in the presence of a catalytic amount of Cp2TiCl2 leads to the corresponding reduction products in high yields. Cp2TiH intermediate was proposed to account for this observation.
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