Reactions with aziridines XXI The (Michaelis-)arbusov reaction with N-acyl aziridines and other amidoethylations at phosphorus. |
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| Authors: | Helmut Stamm Gerhard Gerster |
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| Institution: | Pharmazeutisch-Chemisches Institut, University of Heidelberg Im Neuenheimer Feld 364, D-6900Heidelberg, W. Germany |
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| Abstract: | Heating trialkyl phosphites with N-acyl aziridines produces dialkyl 2-amidoethyl-phosphonates bearing one of the phosphite alkyl groups on nitrogen. Other alkoxy phosphines behave analogously. Dialkyl phosphites furnish the same type of products devoid of the N-alkyl group. |
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