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The reaction of eremanthin and isoeremanthin with bromine. Unprecedented simultaneous addition of Br2 to two isolated but topographically related double bonds.
Authors:Marcos Garcia  FWelbaneide L Machado  Lélio A Maçaira  Jaime A Rabi
Institution:Núcleo de Pesquisas de Produtos Naturais, Centro de Ciências da Saúde, Bloco H, Universidade Federal do Rio de Janeiro, Ilha do Fundão, Rio de Janeiro, Brasil.
Abstract:The reaction of 1 with Br2 in CHCl3 proceeds with the simultaneous and stereospecific incorporation of two moles of Br2 to give 2 thus providing strong experimental evidence for the existence of Br3.
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