Hammett-correlations,solvent effects and stereochemistry of the thermal decarboxylation of 2-oxetanones - evidence for a zwitterionic intermediate |
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Authors: | Johann Mulzer Matthias Zippel |
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Affiliation: | Institut für Organische Chemie der Universität, Karlstrasse 23, D 8000 München 2, West Germany |
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Abstract: | Kinetic and stereochemical data of the thermal decarboxylation of 2-oxetanones ( and ) indicate that the reaction proceeds via a zwitterionic intermediate Z. |
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