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Hammett-correlations,solvent effects and stereochemistry of the thermal decarboxylation of 2-oxetanones - evidence for a zwitterionic intermediate
Authors:Johann Mulzer  Matthias Zippel
Affiliation:Institut für Organische Chemie der Universität, Karlstrasse 23, D 8000 München 2, West Germany
Abstract:Kinetic and stereochemical data of the thermal decarboxylation of 2-oxetanones (1 and 2) indicate that the reaction proceeds via a zwitterionic intermediate Z.
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