Bis-thallium(I) porphyrin complexes |
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Authors: | Kevin M. Smith Jan-Ji Lai |
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Affiliation: | Department of Chemistry, University of California at Davis, Davis, California 95616, USA. |
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Abstract: | Treatment of octaethylporphyrin () or tetraphenylporphyrin () with more than two equiv of thallium(I) ethoxide gives the corresponding stable bis[thallium(I)] porphyrin complexes () and (), respectively; these thallium(I) porphyrins are shown to have very different chemical and spectroscopic properties than do the corresponding thallium(III) porphyrin complexes. |
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